ORNL Microscopy Pencils Patterns in Polymers at the Nanoscale
Scientists at the U.S. Department of Energy’s Oak Ridge National Laboratory have used advanced microscopy to carve out nanoscale designs on the surface of a new class of ionic polymer materials for the first time. The study provides new evidence that atomic force microscopy, or AFM, could be used to precisely fabricate materials needed for increasingly smaller devices. Polymerized ionic liquids have potential applications in technologies such as lithium batteries, transistors and solar cells because of their high ionic conductivity and unique structure. But many aspects of the recently discovered materials are still not well understood. When ORNL researchers used an atomic force microscope to begin characterizing the properties of polymerized ionic liquid thin films, the experiment yielded some surprising results.
“We were expecting to measure ionic conductivity, and instead we found that we were forming holes on the surface,” said ORNL’s Vera Bocharova, corresponding author on the study published in Advanced Functional Materials. “Then we started to think about how this might have great applications in nanofabrication.” Nanolithography is the dominant technique used by industry for nanofabrication, but its size limitations are leading researchers to explore other methods such as AFM. “This study is part of our search for alternative methods and materials that can be used to create smaller sized objects,” Bocharova said. “For example, our technique might be interesting for the miniaturization of semiconductor technology.”